Assessment of Physical and Chemical Properties in Northern Refineries' Water
Abstract
This study investigates the physical and chemical characteristics of industrial wastewater from the Northern Refineries Company over a six-month period, aiming to inform the design of appropriate treatment units. Semi-monthly samples were collected from January to July 2023, revealing temperatures ranging from 19 to 38 degrees Celsius, turbidity from 4.1 to 31.2 NTU, and electrical conductivity from 623 to 1517 µS/cm. Total dissolved solids varied between 450 and 980 mg/L, pH ranged from 6.8 to 7.7, and dissolved oxygen levels were notably high, between 1.4 and 7 mg/L. Chloride ion levels 16-19.3 mg/L mostly fell below permissible limits, as did sulfate ions. Phosphate concentrations ranged from 0.01 to 0.14 mg/L, while oil residues fluctuated between 0.54 and 124 mg/L. This research highlights the need for tailored wastewater treatment strategies to address specific contaminants and optimize environmental protection efforts in industrial settings.
References
USEPA, "Methods for Chemical Analysis of Water and Wastes," Environmental Monitoring and Support Laboratory, Cincinnati, Ohio, USA, USEPA-600/4-79-020, 1983, pp. 365.1-1 and .4-1.
N.A.S. Al-Hamdani, "Application of Water Quality Indicators to Assess the Water Quality of a Number of Wells on the Left Coast of the City of Mosul, Iraq," M.S. thesis, College of Environmental Sciences and Technologies, University of Mosul, Iraq, 2020.
H.T. Al-Saad, S. Al-Taein, M. Al-Hello, and A. DouAbul, "Hydrocarbons and Trace Elements in the Waters and Sediments of the Marshland of Southern Iraq," Mesopotamian Journal of Marine Science, vol. 24, no. 2, pp. 126-139, 2009.
A.Y.T. Al-Safawi and Y. Reda, "Qualitative Evaluation of Tigris River Water Using Water Quality Factor WQI for Drinking Purposes of Nineveh Governorate, Northern Iraq," in Proceedings of the 7th International Conference of the Water Resources Research Center, University of University, 2018, pp. 189-200.
N.M. Azeez and A.A. Sabbar, "Efficiency of Duckweed (Lemna minor L.) in Phytotreatment of Wastewater Pollutants from Basrah Oil Refinery," Journal of Applied Phytotechnology in Environmental Sanitation, vol. 1, no. 4, pp. 163-172, 2012.
Hach Company/Hach Lange GmbH, "Tetraphenylborate, Method: 8049," Edition 1, DOC316.53.01339, 2014.
Hach Company/Hach Lange GmbH, "Mercuric Thiocyanate, Method: 8113," Edition 9, DOC316.53.01017, 2018.
USEPA, J.W. O'Dell, "Method 375.2, Revision 2.0: Determination of Sulfate by Automated Colorimetry," 375.5, pp. 1-11, 1993.
USEPA, "Approved for Wastewater Analyses," Standard Method 5220 D, Federal Register, vol. 45, no. 78, pp. 26811-26812, 1980.
Hach Company, "Total Petroleum Hydrocarbons TPH: Method 10050," 3rd ed. Loveland, CO, USA: Hach Company, 2020.
O. Osibanjo, A.P. Daso, and A.M. Gbadebo, "The Impact of Industries on Surface Water Quality of River Ona and River Alaro in Oluyole Industrial Estate, Ibadan, Nigeria," African Journal of Biotechnology, vol. 10, no. 4, pp. 696-702, 2011.
S. Pandey and J. Ramontja, "Natural Bentonite Clay and Its Composites for Dye Removal: Current State and Future Potential," American Journal of Chemistry and Applications, vol. 3, no. 2, pp. 8-19, 2016.
P.R. Robinson and E.I. Shaheen, "Environmental Pollution Control: Practical Advances in Petroleum Processing," pp. 395-447, 2006.
A. Saliot, C. Andre, A. Fevrier, M. Goutx, and M. Tissier, "Analysis and Budget of Biogeochemical Markers in Dissolved, Small and Large Size Suspended Matter in the Ocean," in Advances in Organic Geochemistry, John Wiley Chichester, pp. 251-258, 1983.
T.H.Y. Tebbutt, "Principles of Water Quality Control," 6th ed. London, UK: Butterworth Heinemann, p. 273, 1998.
M. Varol, B. Gökot, A. Bekleyen, and B. Şen, "Spatial and Temporal Variations in Surface Water Quality of the Dam Reservoirs in the Tigris River Basin, Turkey," Catena, vol. 92, pp. 11-21, 2012.